A flash
drum is a vessel in which gravity is allowed to separate a liquid and a gas. A throttling
device can be used to reduce the pressure on a liquid stream to produce a two-phase
mixture. |
|
The two-phase mixture enters the flash drum where the liquid settles to the bottom and the vapor rises to the top. Because the vapor and liquid
phases are allowed to reach equilibrium, the vapor
and liquid leaving a flash drum |
|
are both saturated.
Consider the system in the diagram shown below. |
|
|
|
|
|
|
|
|
|
|
|
|
|
Calculate the power output of the turbine and the entropy generation rate for the valve, for the flash drum and for the turbine. Which unit or units generate a large amount of entropy? |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Read : |
This is a complicated problem just because it
is an ensemble of three
processes. Drawing a good flow diagram that includes all the given information is essential. Fortunately, the problem statement includes a good flow diagram. |
|
|
Start from State 1 because you know a lot of
information about this stream. The valve behaves as a throttling valve. Apply mass and energy balances
to the flash drum to
determine m3 and m4. Use the isentropic efficiency to calculate H5 and then use H5 to get x5. Application of the 1st Law to the turbine yields Wturb. |
|
|
To get the correct entropy
generated, you must be very accuarate
in your calculations. Do not round off
until the very end. Save the intermediate results in your
calculator memory or use Excel. |
|
|
|
|
|
|
|
|
|
|
|
|
Given: |
P1 |
240 |
lbf/in2 |
|
|
P2 |
70 |
lbf /
in2 |
|
|
|
T1 |
80 |
oF |
|
|
P3 |
70 |
lbf /
in2 |
|
|
|
m1 |
5 |
lbm/s |
|
|
P4 |
70 |
lbf /
in2 |
|
|
|
hS, turb |
0.88 |
|
|
|
P5 |
20 |
lbf /
in2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
Find: |
a.) |
Wturb |
? |
Btu/s |
|
b.) |
(Sgen)valve |
? |
Btu / s-oR |
|
|
|
|
|
|
|
|
(Sgen)flash |
? |
Btu / s-oR |
|
|
|
|
|
|
|
|
(Sgen)turb |
? |
Btu / s-oR |
|
|
|
|
|
|
|
|
|
|
|
|
Diagram: |
The necessary flow
diagram was provided in the problem statement. |
|
|
|
|
|
|
|
|
|
|
|
|
Assumptions: |
1 - |
Each component
operates at steady-state with
negligible heat transfer between the flowing fluid and the surroundings. |
|
|
|
2 - |
Kinetic and potential energy changes
are negligible. |
|
|
|
3 - |
The expansion across the valve is an isenthalpic throttling process. |
|
|
|
|
|
|
|
|
|
|
|
|
Equations
/ Data / Solve: |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Part a.) |
Let's begin by
applying the steady-state mass balance equation to the valve, the flash drum and the turbine, one unit at a time. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eqn 1 |
|
|
Eqn 2 |
|
|
Eqn 3 |
|
|
|
|
|
|
|
|
|
|
|
|
|
Next, apply the 1st Law to the turbine. The turbine is a steady-state, SISO process with negligible changes in kinetic and potential energies. The appropriate form of the 1st Law is: |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eqn 4 |
|
|
|
|
|
|
|
|
|
|
|
|
|
In Eqn
4, m5 was eliminated using Eqn 3. Because the turbine is also assumed to be adiabatic, Qturb = 0 and Eqn
4 becomes: |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eqn 5 |
|
|
|
|
|
|
|
|
|
|
|
|
|
We can lookup H4 in the Ammonia Tables or NIST Webbook because we know it is a saturated
vapor at 70 psia. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
H4 |
622.25 |
Btu/lbm |
|
|
|
|
|
|
|
|
|
|
|
|
|
We must use the isentropic efficiency of the turbine to determine H5 because we only know the value of one intensive variable at state 5 (P5). |
|
|
|
|
|
|
|
|
|
|
|
|
|
Isentropic
efficiency applied to
our turbine is
defined by: |
|
Eqn 6 |
|
|
|
|
|
|
|
|
|
|
|
|
|
We can solve Eqn 6 for H5, as follows: |
|
Eqn 7 |
|
|
|
|
|
|
|
|
|
|
H5S is the enthalpy of the effluent (at P2) from an adiabatic, isentropic turbine that has the same feed as
the actual turbine. Because this hypothetical turbine
is isentropic: S5S = S4 |
|
|
|
|
|
|
|
|
|
|
|
|
|
We can look up S4 in the Ammonia Tables or the NIST Webbook : |
S4 |
1.2651 |
Btu lbm-oR |
|
|
|
|
|
|
|
|
S5S |
1.2651 |
Btu lbm-oR |
|
|
|
|
|
|
|
|
|
|
|
|
|
Now, we know the
values of two intensive properties at state 5S, so we can determine the
values of other properties at this state, such as T5S and H5S, by interpolating on the Ammonia Tables or the NIST Webbook. We begin by
determining the phases
present. |
|
|
|
|
At P = 20 psia : |
Ssat liq |
0.057608 |
Btu/lbm-oR |
Since Ssat liq < S5 < Ssat vap, state 5S
is a saturated mixture. |
|
|
Ssat vap |
1.3691 |
Btu/lbm-oR |
|
|
|
|
|
|
|
Determine x5S from the specific entropy, using: |
|
Eqn 8 |
|
|
|
|
x5S |
0.9207 |
lbm vap/lbm |
|
|
|
Then, we can use
the
quality to determine H5S, using: |
|
|
Eqn 9 |
|
|
|
|
At P = 20 psia : |
Hsat liq |
24.887 |
Btu/lbm |
|
|
|
Hsat vap |
605.98 |
Btu/lbm |
|
H5S |
559.90 |
Btu/lbm |
|
|
|
|
|
|
|
|
|
|
|
|
|
Now, we can use Eqn 7 to evaluate H5 : |
|
|
H5 |
567.38 |
Btu/lbm |
|
|
|
|
|
|
|
|
|
|
|
|
|
Next, we need to
evaluate m4. Combine Eqns 1 & 2 to
get : |
|
|
Eqn 10 |
|
|
|
|
|
|
|
|
|
|
|
|
|
We know m1, so we need to find m3 to calculate m4. |
|
|
We can determine m3 by applying the 1st Law to the flash drum. The flash drum is adiabatic, operates at steady-state, no shaft
work crosses it boundaries and changes in kinetic and potential energies are negligible. Therefore, the
appropriate form of the 1st Law is: |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eqn 11 |
|
|
|
|
|
|
|
|
|
|
|
|
|
Use Eqn 10 to eliminate m4 from Eqn 11 and use Eqn 1 to eliminate m2 from Eqn 11 and you are left with: |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eqn 12 |
|
|
|
|
|
|
|
|
|
|
|
|
|
We can solve Eqn 12 for m3 , as follows: |
|
|
Eqn 13 |
|
|
|
|
|
|
|
|
|
|
|
|
|
We can lookup the specific enthalpies in states 1 and 3 in the Ammonia
Tables or the NIST
Webbook and we already know H4. Then, we can plug
these values into Eqn 13
to evaluate m3 : |
|
|
|
|
|
|
|
|
|
|
|
|
|
H1 |
131.96 |
Btu/lbm |
|
|
|
|
|
|
|
|
H3 |
84.109 |
Btu/lbm |
|
|
|
m3 |
4.56 |
lbm/s |
|
|
|
|
|
|
|
|
|
|
|
|
|
Next we can evaluate m4 from Eqn 10: |
|
m4 |
0.44 |
lbm/s |
|
|
|
|
|
|
|
|
|
|
|
|
|
At last, we can plug
values back into Eqn 5 to
complete part (a) : |
Wturb |
24.39 |
Btu/s |
|
|
|
|
|
|
|
|
Part b.) |
The entropy
generation rate is defined in the 2nd Law as: |
|
|
Eqn 14 |
|
|
|
|
|
|
|
|
|
|
Since we assumed that
each of our three
processes was adiabatic, Eqn 14 simplifies to: |
|
|
Eqn 15 |
|
|
|
|
|
|
|
|
|
Apply Eqn 15 to each of the three processes: |
|
Eqn 16 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eqn 17 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eqn 18 |
|
|
|
|
|
|
|
|
|
|
|
|
|
At this point, we have
determined the state of all five streams in this process, so we can use the Ammonia Tables or the NIST Webbook to evaluate the entropy of each. |
|
|
|
|
|
|
|
|
|
|
|
|
|
The specific entropies of streams 1, 3 and 4 come straight out of the Ammonia
Tables or NIST Webbook. |
|
|
|
|
|
|
|
|
|
|
|
|
|
S1 |
0.27391 |
Btu / lbm -oR |
|
|
S3 |
0.18317 |
Btu / lbm -oR |
|
|
|
|
S4 |
1.2651 |
Btu / lbm -oR |
|
|
|
|
|
|
|
|
|
For S5, we must first determine the quality using: |
|
Eqn 19 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
x5 |
0.9336 |
lbm vap/lbm |
|
|
|
|
|
|
|
|
|
|
|
|
Then we can evaluate S5 using : |
|
|
Eqn 20 |
|
|
|
|
|
|
|
|
|
|
|
S5 |
1.2820 |
Btu / lbm -oR |
|
|
|
|
|
|
|
|
|
|
|
|
In order to determine S2, we must apply the 1st Law to the valve. We assume the valve operates at steady-state, is adiabatic, exhibits negligible changes in kinetic or potential energies and involves no shaft
work. Under
these conditions, the 1st Law tells us that the valve is an isenthalpic throttling device. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eqn 21 |
|
|
|
|
H2 |
131.96 |
Btu/lbm |
|
|
|
|
|
|
|
|
|
|
|
|
|
Now, we know the
values of two intensive properties at state 2, so we can determine the
values of other properties at this state, such as S2 , by interpolating on the Ammonia Tables or the NIST Webbook. We begin by
determining the phases
present. |
|
|
|
|
At P = 70 psia : |
Hsat liq |
84.109 |
Btu/lbm |
|
Since Hsat liq < H2 < Hsat vap, state 2
is a saturated mixture. |
|
|
Hsat vap |
622.25 |
Btu/lbm |
|
|
|
|
|
|
|
|
Determine x2 from the specific entropy, using: |
|
|
Eqn 22 |
|
|
|
|
x2 |
0.08892 |
lbm vap/lbm |
|
|
|
Then, we can use
the
quality to determine S2, using: |
|
|
Eqn 23 |
|
|
|
|
At P = 70 psia : |
Ssat liq |
0.18317 |
Btu/lbm-oR |
|
|
|
Ssat vap |
1.2651 |
Btu/lbm-oR |
S2 |
0.27938 |
Btu/lbm-oR |
|
|
|
|
|
|
Finally, we have all
the values necessary to plug into Eqns 16-18 to evaluate the entropy generation in each device and then Eqn 24 to evaluate the lost work in
each device. |
|
|
|
|
|
|
|
|
|
|
|
|
|
(Sgen)valve |
0.02734 |
Btu / s-oR |
|
|
|
(Sgen)turb |
0.00751 |
Btu / s-oR |
|
|
(Sgen)flash |
0.00000 |
Btu / s-oR |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Verify: |
The assumptions made
in the solution of this problem cannot be verified with the given
information. |
|
|
|
|
|
|
|
|
|
|
|
|
Answers: |
a.) |
Wturb |
24.4 |
Btu/s |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
b.) |
(Sgen)valve |
0.0273 |
Btu / s-oR |
The expansion valve generates the most entropy. |
|
|
|
(Sgen)flash |
0.00000 |
Btu / s-oR |
|
|
|
|
|
|
|
|
(Sgen)turb |
0.00751 |
Btu / s-oR |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|